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1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

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乌洛托品与碘化镧配合物的合成、表征及抗菌活性研究

彭鹏 , 刘斌 , 王丽 , 张晨鼎

稀土 doi:10.3969/j.issn.1004-0277.2002.06.003

报道了配合物LaI3*C6H12N4*HI*13H2O的新的合成方法,通过元素分析、X射线粉末衍射、红外光谱、核磁共振谱、质谱、差热椚戎胤治?确定了配合物的组成和结构,首次测定了配体和配合物的抗菌活性.

关键词: 碘化镧 , 乌洛托品 , 配合物 , 抗菌活性

镧(Ⅲ)与硫脲配合物的合成、表征及抗菌活性研究

彭鹏 , 刘斌 , 王丽 , 张晨鼎

稀土 doi:10.3969/j.issn.1004-0277.2002.03.010

本文报道了配合物LaI3·2CS(NH2)2·10H2O的新的合成方法,通过元素分析、X射线粉末衍射、红外光谱、核磁共振谱、质谱、差热-热重分析,确定了配合物的组成和结构,首次测定了配体和配合物的抗菌活性.

关键词: 碘化镧 , 硫脲 , 配合物 , 抗菌活性

强制对流作用下多晶粒生长的相场模拟

袁训锋 , 丁雨田

材料导报

采用Tong和Beckermann等提出的耦合流场相场模型对纯镍凝固中多晶粒枝晶的生长过程进行模拟,研究了多晶粒枝晶的生长形貌和温度分布.结果表明,熔体流动显著改变凝固前沿的传热,从而影响枝晶生长.受熔体流动和多晶粒之间相互影响的共同作用,枝晶在4个最优生长方向上的形貌呈现不对称;熔体流动还改变了枝晶的水平最优生长方向,使得水平主枝向上游倾斜;此外,二次枝晶出现径向熔化和轴向熔化等粗化方式.

关键词: 相场法 , 强制对流 , 多晶粒 , 凝固

STUDY ON THE THREESTAGE CREEP OF THE DD3SINGLE CRYSTAL SUPERALLOY

Author X.A. Zhang1) , H.Q. Xia1) , Z.T. Wu1) , Y.F. Han1) , R. Shi2) and G.X. Hu2) \= 1) Mechanical Properties Laboratory , Beijing Institute of Aeronautical Materials , Beijing 100095 , China2) The State Education Commission Open Research Laboratory for High Temperature

金属学报(英文版)

Materials and Testing, Shanghai Jiao Tong University, Shanghai 200030, ChinaManuscript received 18 October 1998 The threestage creep behavior of DD3 single crystal superalloy had been studied. The results show that the creeprupture properties of DD3 single crystal satisfy the requirements for high performance turbine blade application. The influence of crystal orientation on the creeprupture property of DD3 single crystal was tested and discussed. An engineering criterion to evaluate the regimes of secondary and tertiary creep is proposed, and this method gives a reasonable result for practical applications. The fractography and TEM micrography of the tested specimens had been studied, and it is determined that the glidecontrolled creep is the basic creep mechanism of DD3 single crystal at intermediate temperature, but the thermally activated processes become dominant at higher temperature.

关键词: threestage creep curve , null , null , null

Crystallographic Tailoring of Graphene by Nonmetal SiO(x) Nanoparticles

Journal of the American Chemical Society

In this communication, we demonstrate nonmetal SiO(x) nanoparticles (NPs) can tailor few-layer graphenes (FLGs) into graphene nanoribbons (GNRs) and regular pieces with smooth edges. The tailoring of graphene is realized by the movements of SiO(x) NPs along the graphene lattice in the atmosphere of H(2), and the tailored trenches exhibit high selectivity of the crystallographic orientation compared to the reported metal. NPs. The low tailoring rate and the tong lifetime provide great potential for accurate control of the trench length or the length of the tailored GNRs. As a result, smooth GNRs with a length of several micrometers and a width narrower than 10 nm are obtained. A catalytic hydrogenation mechanism is proposed for the tailoring of graphene by SiO(x) NPs. These findings open up the possibility for atomically precise graphene device fabrication without metal, contamination and indicate the potential catalytic activity of nonmetal Nips for the hydrogenation of carbon materials.

关键词: nanoribbons;hydrogenation;graphite

LaBr3晶体本征点缺陷研究

姜威 , 刘廷禹 , 孙颖 , 孙羽

人工晶体学报

基于密度泛函理论平面波赝势法对LaBr3晶体本征点缺陷进行了系统研究.通过第一性原理和热动力学方法,计算得到了不同温度及溴分压下LaBr3晶体中本征点缺陷的缺陷形成能,并讨论了不同环境条件下本征点缺陷的形成能随费米能级的变化关系.计算结果表明,当费米能级位于导带底附近时,LaBr3晶体中的主要点缺陷为Lai…能级位于价带顶附近时,LaBr3晶体中主要的点缺陷为Vlao…VBr在高温/低溴分压相对稳定,Vla在低温/高溴分压更稳定.本文还做出了最稳定点缺陷随温度、溴分压及费米能级变化的三维空间分布图,清晰地呈现了不同条件下,该晶体最可能出现的点缺陷类型,从而为调控晶体的点缺陷改善晶体光学性能提供参考.

关键词: LaBr3晶体 , 密度泛函理论 , 点缺陷 , 热力学

桐马环氧玻璃丝粉云母绝缘材料的耐盐雾湿热老化特性

付强 , 孔繁荣 , 陈庆国

复合材料学报

为了研究海洋能电机主绝缘材料耐盐雾湿热老化能力,对电机多胶模压(Resin Rich Molding,RRM)桐马环氧玻璃丝粉云母(Tong ma Epoxy Glass Fiber Power Mica,TEGM)绝缘材料进行模拟海洋气候的盐雾湿热老化试验,测试了不同老化周期下材料的吸水率变化,并结合扫描电子显微镜(Scanning Electron Microscope,SEM)的观测结果分析了材料老化前后微观形貌的变化.利用宽频介电阻抗谱仪测试不同老化周期和不同测试温度下的TEGM绝缘材料的频域介电参数变化,并运用电介质极化理论分析老化前后的微观结构形态变化和宏观介电性能之间的关系.研究结果表明,TEGM绝缘试样老化过程中的吸水性呈现快速吸湿、缓慢吸湿和饱和吸湿3个阶段;随着老化时间的延长,材料相对介电常数和介质损耗因数呈上升趋势,利用频域介电谱(Frequency Domain Spectroscopy,FDS)曲线可较好反映绝缘材料的老化状态;通过对测试数据的拟合,得到老化绝缘材料的介电参数与材料吸水率在低频下存在的二次方程关系.

关键词: 盐雾湿热老化 , 频域介电谱 , 多胶模压 , 桐马环氧玻璃丝粉云母 , 绝缘材料 , 老化 , 吸水率

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